ACE - A single point or spot on a playing card or die.
EVE - The day or night before, usually used for holidays, such as Christmas Eve.
ICE - Water in frozen (solid) form.
VIA - A main road or highway, especially in ancient Rome. (Mainly used in set phrases, below.).
CHI - The twenty-second letter of the Classical and Modern Greek alphabets, and the twenty-third letter of Old and Ancient alphabets.
VIE - To rival; to struggle for superiority; to contend; to compete eagerly so as to gain something.
VAC - A vacation.
CAVE - A large, naturally-occurring cavity formed underground, or in the face of a cliff or a hillside.
EACH - All; every; qualifying a singular noun, indicating all examples of the thing so named seen as individual or separate items (compare every).
HAVE - To possess, own, hold.
ACHE - To suffer pain; to be the source of, or be in, pain, especially continued dull pain; to be distressed.
HIVE - A structure for housing a swarm of honeybees.
CHIVE - A plant that is perennial (Allium schoenoprasum), related to the onion.
HEAVE - To lift (generally); to raise, or cause to move upwards (particularly in ships or vehicles) or forwards.
ACHIEVE - To obtain (a material thing).